CAS:38465-86-0 | 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate

Molecular Formula:C34H38F6IrP3
Molecular Weight:845.79
Purity:98%
Package:5g/10g/25g/50g/bulk package
Transportation: FeDex/DHL/ocean shipping /clients requirement

Application

Name

1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate

Synonyms

(1Z,5Z)-Cycloocta-1,5-diene;iridium;methyl(diphenyl)phosphane;hexafluorophosphate

CAS

38465-86-0

MDL No

MFCD00064800

Melting Point

224°C dec. (Lit.)

PSA

40.77

LogP

11.55

Appearance

Red Crystalline powder

Sensitivity

Air & Moisture Sensitive

Solubility

Soluble in acetone. Insoluble in water

Storage condition

Under inert gas (nitrogen or Argon) at 2-8°C

InChI

InChI=1S/2C13H13P.C8H12.F6P.Ir/c2*1-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h2*2-11H,1H3;1-2,7-8H,3-6H2;/q;-1;/b;2-1-,8-7-

InChIKey

MUHONFFTSOCMDH-JXNOXZOESA-N

Application:

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate(CAS:38465-86-0) is a cationic Iridium (I) complex employed as a catalyst. (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate has been employed for the isomzerization of allyl ethers of glycerol and glucose to the corresponding 1-propenyl ethers, and this protocol has seen use in other carbohydrate chemistry applications.

References:

1. Oltvoort, J.J., et al. 1981. Synthesis. 1981: 305-308.

2. Spijker, N.M., et al. 1996. Tetrahedron. 52: 5945-5960.

3. Petitou, M., et al. 2001. Chemistry Eur. J. 7: 858-873.

CAS:38465-86-0 | 1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) Hexafluorophosphate

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