CAS:536724-67-1 | [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium,tricyclohexylphosphane

Name:[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium,tricyclohexylphosphane
CAS:536724-67-1
Purity:98%
Molecular Formula:C54H69Cl2N2PRu
Molecular Weight:949.09
Melting Point:159 (d)-162°C
Boiling Point:N/A

Application

Name:[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium,tricyclohexylphosphane

Synonyms:UMICORE M2;NEOLYST M2;

CAS:536724-67-1

Purity:98%

Molecular Formula:C54H69Cl2N2PRu

Molecular Weight:949.09

Melting Point:159 (d)-162°C

Boiling Point:N/A

PSA:20.07

LogP:15.68

Storage condition:2-8°C, protect from light, stored under nitrogen

InChI:InChI=1S/C21H26N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2;

InChI Key:MCNUJWCJGIGFBS-UHFFFAOYSA-L;

Application:Neolyst Dichloride acts as a catalyst in cross-metathesis reactions. In addition it is used in the preparation of Weinreb amide pyrrolidines.

Reference:

Boufroura, H. et al.: J. Org. Chem., 78, 2346 (2013); Lujan, C. et al.: Cat. Sci. Tech., 2, 1027 (2012);

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CAS:536724-67-1 | [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium,tricyclohexylphosphane

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CAS:536724-67-1 | [1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichloro-(3-phenylinden-1-ylidene)ruthenium,tricyclohexylphosphane

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